» Articles » PMID: 24451583

C-H Activation: A Surrogate for Selectivity

Overview
Journal Nat Chem
Specialty Chemistry
Date 2014 Jan 24
PMID 24451583
Citations 2
Authors
Affiliations
Soon will be listed here.
Citing Articles

Synthesis of functionalised isochromans: epoxides as aldehyde surrogates in hexafluoroisopropanol.

Muller C, Horky F, Vayer M, Golushko A, Leboeuf D, Moran J Chem Sci. 2023; 14(11):2983-2989.

PMID: 36937595 PMC: 10016621. DOI: 10.1039/d2sc06692k.


The design of a readily attachable and cleavable molecular scaffold for -selective C-H alkenylation of arene alcohols.

Knight B, Rothbaum J, Ferreira E Chem Sci. 2018; 7(3):1982-1987.

PMID: 29899921 PMC: 5966905. DOI: 10.1039/c5sc03948g.

References
1.
Huang C, Chattopadhyay B, Gevorgyan V . Silanol: a traceless directing group for Pd-catalyzed o-alkenylation of phenols. J Am Chem Soc. 2011; 133(32):12406-9. PMC: 3156791. DOI: 10.1021/ja204924j. View

2.
McMurray L, OHara F, Gaunt M . Recent developments in natural product synthesis using metal-catalysed C-H bond functionalisation. Chem Soc Rev. 2011; 40(4):1885-98. DOI: 10.1039/c1cs15013h. View

3.
He G, Chen G . A practical strategy for the structural diversification of aliphatic scaffolds through the palladium-catalyzed picolinamide-directed remote functionalization of unactivated C(sp3)-H bonds. Angew Chem Int Ed Engl. 2011; 50(22):5192-6. DOI: 10.1002/anie.201100984. View

4.
Engle K, Mei T, Wasa M, Yu J . Weak coordination as a powerful means for developing broadly useful C-H functionalization reactions. Acc Chem Res. 2011; 45(6):788-802. PMC: 3334399. DOI: 10.1021/ar200185g. View

5.
Ghavtadze N, Melkonyan F, Gulevich A, Huang C, Gevorgyan V . Conversion of 1-alkenes into 1,4-diols through an auxiliary-mediated formal homoallylic C-H oxidation. Nat Chem. 2014; 6(2):122-5. PMC: 4157638. DOI: 10.1038/nchem.1841. View