Cold State-selected Molecular Collisions and Reactions
Overview
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Over the past decade, and particularly the past five years, a quiet revolution has been building at the border between atomic physics and experimental quantum chemistry. The rapid development of techniques for producing cold and even ultracold molecules without a perturbing rare-gas cluster shell is now enabling the study of chemical reactions and scattering at the quantum scattering limit with only a few partial waves contributing to the incident channel. Moreover, the ability to perform these experiments with nonthermal distributions comprising one or a few specific states enables the observation and even full control of state-to-state collision rates in this computation-friendly regime: This is perhaps the most elementary study possible of scattering and reaction dynamics.
Imaging Resonance Effects in C + H Collisions Using a Zeeman Decelerator.
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PMID: 38640083 PMC: 11071073. DOI: 10.1021/acs.jpclett.3c03379.
Towards chemistry at absolute zero.
Heazlewood B, Softley T Nat Rev Chem. 2023; 5(2):125-140.
PMID: 37117610 DOI: 10.1038/s41570-020-00239-0.
Ultracold chemical reactions reveal the quantum mechanism of product formation.
Mukherjee N Nature. 2021; 593(7859):344-345.
PMID: 34012078 DOI: 10.1038/d41586-021-01264-9.
Molecules and the Eigenstate Thermalization Hypothesis.
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PMID: 33265762 PMC: 7513195. DOI: 10.3390/e20090673.
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PMID: 31378187 PMC: 6710894. DOI: 10.1098/rsta.2018.0409.