Stepwise Addition of Difluorocarbene to a Transition Metal Centre

Overview

Journal Chem Commun (Camb)

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2013 Dec 11

PMID 24322965

Citations 4

Authors

Graham M Lee

Daniel J Harrison

Ilia Korobkov

R Tom Baker

Affiliations

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Abstract

The Ruppert-Prakash reagent (Me3SiCF3) is used to introduce difluorocarbene (CF2) and tetrafluoroethylene (TFE) ligands to cobalt(I) metal centres, whereby the TFE ligand is generated via [2+1] cycloaddition between [Co]=CF2 and CF2.

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