Copolymerization of Cyclohexene Oxide with CO2 Catalyzed by Tridentate N-heterocyclic Carbene Titanium(IV) Complexes

Overview

Journal Dalton Trans

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2013 Dec 3

PMID 24292280

Citations 3

Authors

Coralie C Quadri

Erwan Le Roux

Affiliations

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Abstract

A new class of complexes based on titanium(IV) bearing a bisanionic mer-tridentate N-heterocyclic carbene ligand were investigated for the copolymerization of cyclohexene oxide with CO2. Upon addition of [PPN]X' salts, all complexes were found to be active and highly selective toward the formation of poly(cyclohexene oxide-alt-carbon dioxide).

Citing Articles

Unsaturated and Benzannulated -Heterocyclic Carbene Complexes of Titanium and Hafnium: Impact on Catalysts Structure and Performance in Copolymerization of Cyclohexene Oxide with CO.

Suresh L, Lalrempuia R, B Ekeli J, Gillis-DHamers F, Tornroos K, Jensen V Molecules. 2020; 25(19).

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Ti(IV)-Tris(phenolate) Catalyst Systems for the Ring-Opening Copolymerization of Cyclohexene Oxide and Carbon Dioxide.

Raman S, Deacy A, Carrodeguas L, Reis N, Kerr R, Phanopoulos A Organometallics. 2020; 39(9):1619-1627.

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NHC Core Pincer Ligands Exhibiting Two Anionic Coordinating Extremities.

Taakili R, Canac Y Molecules. 2020; 25(9).

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