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High-mobility Graphene on Liquid P-block Elements by Ultra-low-loss CVD Growth

Overview
Journal Sci Rep
Specialty Science
Date 2013 Sep 17
PMID 24036929
Citations 8
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Abstract

The high-quality and low-cost of the graphene preparation method decide whether graphene is put into the applications finally. Enormous efforts have been devoted to understand and optimize the CVD process of graphene over various d-block transition metals (e.g. Cu, Ni and Pt). Here we report the growth of uniform high-quality single-layer, single-crystalline graphene flakes and their continuous films over p-block elements (e.g. Ga) liquid films using ambient-pressure chemical vapor deposition. The graphene shows high crystalline quality with electron mobility reaching levels as high as 7400 cm(2) V(-1) s(-1) under ambient conditions. Our employed growth strategy is ultra-low-loss. Only trace amounts of Ga are consumed in the production and transfer of the graphene and expensive film deposition or vacuum systems are not needed. We believe that our research will open up new territory in the field of graphene growth and thus promote its practical application.

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References
1.
Liu M, Zhang Y, Chen Y, Gao Y, Gao T, Ma D . Thinning segregated graphene layers on high carbon solubility substrates of rhodium foils by tuning the quenching process. ACS Nano. 2012; 6(12):10581-9. DOI: 10.1021/nn3047154. View

2.
Robertson A, Warner J . Hexagonal single crystal domains of few-layer graphene on copper foils. Nano Lett. 2011; 11(3):1182-9. DOI: 10.1021/nl104142k. View

3.
Dai B, Fu L, Zou Z, Wang M, Xu H, Wang S . Rational design of a binary metal alloy for chemical vapour deposition growth of uniform single-layer graphene. Nat Commun. 2011; 2:522. DOI: 10.1038/ncomms1539. View

4.
Vlassiouk I, Regmi M, Fulvio P, Dai S, Datskos P, Eres G . Role of hydrogen in chemical vapor deposition growth of large single-crystal graphene. ACS Nano. 2011; 5(7):6069-76. DOI: 10.1021/nn201978y. View

5.
Ago H, Ito Y, Mizuta N, Yoshida K, Hu B, Orofeo C . Epitaxial chemical vapor deposition growth of single-layer graphene over cobalt film crystallized on sapphire. ACS Nano. 2010; 4(12):7407-14. DOI: 10.1021/nn102519b. View