A Ferrocene-porphyrin Ligand for Multi-transduction Chemical Sensor Development

Overview

Journal Sensors (Basel)

Publisher MDPI

Specialty Biotechnology

Date 2013 May 9

PMID 23653052

Citations 5

Authors

Larisa Lvova

Pierluca Galloni

Barbara Floris

Ingemar Lundstrom

Roberto Paolesse

Corrado Di Natale

Affiliations

Soon will be listed here.

Abstract

5,10,15,20-Tetraferrocenyl porphyrin, H2TFcP, a simple example of a donor-acceptor system, was tested as ligand for the development of a novel multi-transduction chemical sensors aimed at the determination of transition metal ions. The fluorescence energy transfer between ferrocene donor and porphyrin acceptor sub-units was considered. The simultaneously measured optical and potentiometric responses of solvent polymeric membranes based on H2TFcP permitted the detection of lead ions in sample solutions, in the concentration range from 2.7 × 10(-7) to 3.0 × 10(-3) M. The detection limit of lead determination was 0.27 μM, low enough to perform the direct analysis of Pb2+ in natural waters.

Citing Articles

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