Selective Aerobic Oxidation of Amines to Imines by TiO2 Photocatalysis in Water

Overview

Journal Chem Commun (Camb)

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2013 Apr 26

PMID 23615815

Citations 8

Authors

Ning Li

Xianjun Lang

Wanhong Ma

Hongwei Ji

Chuncheng Chen

Jincai Zhao

Affiliations

Soon will be listed here.

Abstract

Selective oxidation of benzylic amines to imines with atmospheric O2 is achieved in water on TiO2 under UV irradiation. The afforded imine could be easily separated and TiO2 can be recycled by filtration. To scale up, gram-scale imine products can be obtained.

Citing Articles

Facile Conversion of Aryl Amines Having No α-Methylene to Aryl Nitriles.

Moirangthem S, Ahanthem D, Khongbantabam S, Laitonjam W ACS Omega. 2022; 7(35):31348-31351.

PMID: 36092588 PMC: 9453805. DOI: 10.1021/acsomega.2c03622.

Cultivation of a Cu/HMPC catalyst from a hyperaccumulating mustard plant for highly efficient and selective coupling reactions under mild conditions.

Gopiraman M, Wei K, Zhang K, Chung I, Kim I RSC Adv. 2022; 8(9):4531-4547.

PMID: 35539525 PMC: 9077870. DOI: 10.1039/c7ra12470h.

Metal-free C(sp)-H functionalization of sulfonamides strain-release rearrangement.

Hu J, Yang X, Shi S, Cheng B, Luo X, Lan Y Chem Sci. 2021; 12(11):4034-4040.

PMID: 34163674 PMC: 8179522. DOI: 10.1039/d0sc06603f.

Enhanced Photocatalytic Efficiency of a Least Active Ag-TiO by Amine Adsorption.

Mogal S, Shah D, Mukherjee T, Shripathi T, Kumar Mishra M ACS Omega. 2019; 3(10):12802-12812.

PMID: 31458006 PMC: 6644989. DOI: 10.1021/acsomega.8b01890.

Photocatalytic Dehydrogenation of Primary Alcohols: Selectivity Goes against Adsorptivity.

Ma D, Liu A, Lu C, Chen C ACS Omega. 2019; 2(8):4161-4172.

PMID: 31457713 PMC: 6641877. DOI: 10.1021/acsomega.7b00754.