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Introduction to Optical Methods for Characterizing Liquid Crystals at Interfaces

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Journal Langmuir
Specialty Chemistry
Date 2013 Jan 26
PMID 23347378
Citations 27
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Abstract

This Instructional Review describes methods and underlying principles that can be used to characterize both the orientations assumed spontaneously by liquid crystals (LCs) at interfaces and the strength with which the LCs are held in those orientations (so-called anchoring energies). The application of these methods to several different classes of LC interfaces is described, including solid and aqueous interfaces as well as planar and nonplanar interfaces (such as those that define a LC-in-water emulsion droplet). These methods, which enable fundamental studies of the ordering of LCs at polymeric, chemically functionalized, and biomolecular interfaces, are described in this Instructional Review on a level that can be easily understood by a nonexpert reader such as an undergraduate or graduate student. We focus on optical methods because they are based on instrumentation that is found widely in research and teaching laboratories.

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References
1.
Bai Y, Abbott N . Recent advances in colloidal and interfacial phenomena involving liquid crystals. Langmuir. 2010; 27(10):5719-38. PMC: 3089817. DOI: 10.1021/la103301d. View

2.
Goyal R, Denn M . Orientational multiplicity and transitions in liquid crystalline droplets. Phys Rev E Stat Nonlin Soft Matter Phys. 2007; 75(2 Pt 1):021704. DOI: 10.1103/PhysRevE.75.021704. View

3.
Karanikolos G, Alexandridis P, Mallory R, Petrou A, Mountziaris T . Templated synthesis of ZnSe nanostructures using lyotropic liquid crystals. Nanotechnology. 2010; 16(10):2372-80. DOI: 10.1088/0957-4484/16/10/063. View

4.
Lockwood N, de Pablo J, Abbott N . Influence of surfactant tail branching and organization on the orientation of liquid crystals at aqueous-liquid crystal interfaces. Langmuir. 2005; 21(15):6805-14. DOI: 10.1021/la050231p. View

5.
Lowe A, Abbott N . Liquid Crystalline Materials for Biological Applications. Chem Mater. 2012; 24(5):746-758. PMC: 3339119. DOI: 10.1021/cm202632m. View