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Cooperative Supramolecular Polymerization Driven by Metallophilic Pd···Pd Interactions

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Journal J Am Chem Soc
Specialty Chemistry
Date 2013 Jan 26
PMID 23347358
Citations 17
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Abstract

A new oligophenyleneethynylene (OPE)-based Pd(II) pyridyl complex has been synthesized, and its self-assembly has been investigated in solution, in the bulk state, and on surfaces. Detailed analysis of concentration- and temperature-dependent UV-vis studies in methylcyclohexane supported by DFT calculations demonstrate for the first time that cooperative supramolecular polymerization processes can be driven by metallophilic interactions.

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