Polariton Dynamics Under Strong Light-molecule Coupling

Overview

Journal Chemphyschem

Specialty Chemistry

Date 2012 Dec 13

PMID 23233286

Citations 41

Authors

Tal Schwartz

James A Hutchison

Jeremie Leonard

Cyriaque Genet

Stefan Haacke

Thomas W Ebbesen

Affiliations

Soon will be listed here.

Abstract

We present a comprehensive experimental study of the photophysical properties of a molecule-cavity system under strong coupling conditions, using steady-state and femtosecond time-resolved emission and absorption techniques to selectively excite the lower and upper polaritons as well as the reservoir of uncoupled molecules. Our results demonstrate the complex decay routes in such hybrid systems and that, contrary to expectations, the lower polariton is intrinsically long-lived.

Citing Articles

Photochemical initiation of polariton-mediated exciton propagation.

Sokolovskii I, Groenhof G Nanophotonics. 2024; 13(14):2687-2694.

PMID: 39678664 PMC: 11636319. DOI: 10.1515/nanoph-2023-0684.

Mechanism of Molecular Polariton Decoherence in the Collective Light-Matter Couplings Regime.

Chng B, Ying W, Lai Y, Vamivakas A, Cundiff S, Krauss T J Phys Chem Lett. 2024; 15(47):11773-11783.

PMID: 39556114 PMC: 11613686. DOI: 10.1021/acs.jpclett.4c03049.

Cavity Controlled Upconversion in CdSe Nanoplatelet Polaritons.

Amin M, Koessler E, Morshed O, Awan F, Cogan N, Collison R ACS Nano. 2024; 18(32):21388-21398.

PMID: 39078943 PMC: 11328175. DOI: 10.1021/acsnano.4c05871.

Molecular Strong Coupling and Cavity Finesse.

Menghrajani K, Vasista A, Tan W, Thomas P, Herrera F, Barnes W J Phys Chem Lett. 2024; 15(29):7449-7457.

PMID: 39008808 PMC: 11284854. DOI: 10.1021/acs.jpclett.4c00782.

Transient Absorption Spectroscopy of Films: Impact of Refractive Index.

Pasanen H, Khan R, Odutola J, Tkachenko N J Phys Chem C Nanomater Interfaces. 2024; 128(15):6167-6179.

PMID: 38655057 PMC: 11037419. DOI: 10.1021/acs.jpcc.4c00981.