Metallo-foldamers with Backbone-coordinative Oxime Peptides: Control of Secondary Structures

Overview

Journal Angew Chem Int Ed Engl

Specialty Chemistry

Date 2012 Nov 17

PMID 23154930

Citations 6

Authors

Shohei Tashiro

Koji Matsuoka

Ai Minoda

Mitsuhiko Shionoya

Affiliations

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Abstract

Metal-mediated secondary structures of peptide-based foldamers were constructed using artificial backbone-coordinative oxime peptides. Complexation of the peptides with Pd(II) afforded several mononuclear and dinuclear secondary structures such as helices and hairpins as confirmed by single-crystal XRD and NMR analyses.

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