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Mechanochemical Synthesis of an Yttrium Based Metal-organic Framework

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Specialty Chemistry
Date 2012 Nov 7
PMID 23128845
Citations 5
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Abstract

For the first time a metal hydride has been used for the preparation of a metal-organic framework. MIL-78 has been synthesized by the solid-state mechanochemical reaction between yttrium hydride and trimesic acid. The process does not involve solvents and does not generate liquid by-products, thus proving the viability of the solid-state approach to the synthesis of MOFs.

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