Synthesis and Engineering Porosity of a Mixed Metal Fe2Ni MIL-88B Metal-organic Framework

Overview

Journal Dalton Trans

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2012 Oct 23

PMID 23086076

Citations 8

Authors

Gia-Thanh Vuong

Minh-Hao Pham

Trong-On Do

Affiliations

Soon will be listed here.

Abstract

A new rational approach has been developed for the synthesis of a mixed metal MIL-88B metal-organic framework based on a neutral mixed metal cluster, such as Fe(2)Ni(μ(3)-O). Unlike the conventional negative charged single metal cluster, the use of the neutral mixed metal cluster as nodes in the framework avoids the need of a compensating anion inside the porous MIL-88B system; thus the mixed metal MIL-88B becomes porous. The flexibility of the mixed metal MIL-88B can be controlled by terminal ligands with different steric hindrance. This allows us to reversibly customize the porosity of the MIL-88B structure at three levels of specific surface area as well as the pore volume.

Citing Articles

Comparison of In Situ and Postsynthetic Formation of MOF-Carbon Composites as Electrocatalysts for the Alkaline Oxygen Evolution Reaction (OER).

Sondermann L, Voggenauer L, Vollrath A, Strothmann T, Janiak C Molecules. 2025; 30(2).

PMID: 39860079 PMC: 11767250. DOI: 10.3390/molecules30020208.

A quest for cytocompatible metal organic frameworks in non-viral gene therapy: Relevance of zeolitic imidazolate framework-8.

Poddar A, Pyreddy S, Polash S, Doherty C, Shukla R Biomater Biosyst. 2023; 8:100065.

PMID: 36824375 PMC: 9934432. DOI: 10.1016/j.bbiosy.2022.100065.

Programmable Drug Release from a Dual-Stimuli Responsive Magnetic Metal-Organic Framework.

Akbar M, Badar M, Zaheer M ACS Omega. 2022; 7(36):32588-32598.

PMID: 36120053 PMC: 9475617. DOI: 10.1021/acsomega.2c04144.

Role of MIL-53(Fe)/hydrated-dehydrated MOF catalyst for electrochemical hydrogen evolution reaction (HER) in alkaline medium and photocatalysis.

Nivetha R, Kollu P, Chandar K, Pitchaimuthu S, Jeong S, Grace A RSC Adv. 2022; 9(6):3215-3223.

PMID: 35518959 PMC: 9059945. DOI: 10.1039/c8ra08208a.

Facile Fabrication of Novel NiFeO@Carbon Composites for Enhanced Adsorption of Emergent Antibiotics.

Lam V, Ngo T, Bach L Materials (Basel). 2021; 14(21).

PMID: 34772240 PMC: 8587843. DOI: 10.3390/ma14216710.