Selective Switchable Iron-catalyzed Hydrosilylation of Carboxylic Acids
Overview
Affiliations
Selective reduction of carboxylic acids either to aldehydes or alcohols is achieved using a one pot procedure based on iron-catalyzed hydrosilylations. Using phenylsilane and (COD)Fe(CO)(3) catalyst under UV-irradiation at rt, alcohols were obtained specifically in good yields, whereas aldehydes were selectively obtained using TMDS and (t-PBO)Fe(CO)(3) catalyst under thermal activation.
Recent advances utilized in artificial switchable catalysis.
Ghorbani-Choghamarani A, Taherinia Z RSC Adv. 2022; 12(36):23595-23617.
PMID: 36090388 PMC: 9389550. DOI: 10.1039/d2ra03842k.
Controlling Chemoselectivity of Catalytic Hydroboration with Light.
Bergamaschi E, Lunic D, McLean L, Hohenadel M, Chen Y, Teskey C Angew Chem Int Ed Engl. 2021; 61(8):e202114482.
PMID: 34905284 PMC: 9305532. DOI: 10.1002/anie.202114482.
Reduction of Carboxylic Acids to Alcohols via Manganese(I) Catalyzed Hydrosilylation.
Antico E, Schlichter P, Werle C, Leitner W JACS Au. 2021; 1(6):742-749.
PMID: 34467330 PMC: 8395667. DOI: 10.1021/jacsau.1c00140.
Storing redox equivalent in the phenalenyl backbone towards catalytic multi-electron reduction.
Bhunia M, Sahoo S, Shaw B, Vaidya S, Pariyar A, Vijaykumar G Chem Sci. 2019; 10(31):7433-7441.
PMID: 31489166 PMC: 6713874. DOI: 10.1039/c9sc02057h.
Hu P, Tan M, Cheng L, Zhao H, Feng R, Gu W Nat Commun. 2019; 10(1):2425.
PMID: 31160563 PMC: 6546739. DOI: 10.1038/s41467-019-10414-7.