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Trichlorido[4-meth-oxy-2,6-bis-(2-pyrimidin-2-yl-κN)phenyl-κC(1)]platinum(IV) Acetonitrile Monosolvate

Overview
Journal Acta Crystallogr Sect E Struct Rep Online
Date 2012 Sep 13
PMID 22969494
Citations 1
Authors
Yang Wu
Dahai Xie
Dengqing Zhang
Xianying Li
Wusong Jin
Affiliations
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Abstract

In the title complex, [Pt(C(15)H(11)N(4)O)Cl(3)]·CH(3)CN, the Pt(IV) ion adopts a distorted octa-hedral coordination geometry defined by a tridentate cyclo-metalated NCN ligand and three Cl atoms. In the crystal, individual mol-ecules are aggregated into a three-dimensional network by C-H⋯Cl hydrogen-bonding inter-actions and π-π stacking inter-actions between the tridentate ligands, the shortest ring centroid-centroid distance being 3.613 Å.

Citing Articles

2-[3-Meth-oxy-5-(pyrimidin-2-yl)phen-yl]pyrimidine.

Hu J, Wu Y, Zhang D, Li X, Jin W Acta Crystallogr Sect E Struct Rep Online. 2013; 69(Pt 3):o333.

PMID: 23476528 PMC: 3588471. DOI: 10.1107/S1600536813002663.

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