Tuning the Breathing Behaviour of MIL-53 by Cation Mixing

Overview

Journal Chem Commun (Camb)

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2012 Sep 13

PMID 22968060

Citations 20

Authors

Farid Nouar

Thomas Devic

Hubert Chevreau

Nathalie Guillou

Emma Gibson

Guillaume Clet

Marco Daturi

Alexandre Vimont

Jean Marc Greneche

Matthew I Breeze

Richard I Walton

Philip L Llewellyn

Christian Serre

Affiliations

Soon will be listed here.

Abstract

A mixed cation MIL-53(Cr-Fe) MOF has been obtained by direct synthesis. Multiple experimental techniques have demonstrated the presence of a genuine mixed phase, leading to a breathing behaviour different from either of the single cation analogues.

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