Characterization of a Thiolato Iron(III) Peroxy Dianion Complex

Overview

Journal Angew Chem Int Ed Engl

Specialty Chemistry

Date 2012 Aug 14

PMID 22888066

Citations 8

Authors

Aidan R McDonald

Katherine M Van Heuvelen

Yisong Guo

Feifei Li

Emile L Bominaar

Eckard Munck

Lawrence Que Jr

Affiliations

Soon will be listed here.

Abstract

Nucleophilic oxidant: The reaction between a thiolato iron(II) complex 1 and superoxide in aprotic solvent at -90 °C yields a novel thiolato iron(III) peroxide intermediate 2, which exhibits unusually high nucleophilic reactivity. Compound 2 is an isomer of the thiolato iron(II) superoxide intermediate that is invoked in the reaction between superoxide reductase and superoxide.

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