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4-Chloro-benzoyl-meso-octa-methyl-calix[2]pyrrolidino[2]pyrrole: an Acyl Chloride Derivative of a Partially Reduced Calix[4] Pyrrole

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Date 2012 May 17
PMID 22590031
Citations 1
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Abstract

In the title compound, C(35)H(47)ClN(4)O, the two pyrrolidine rings have envelope conformations. The conformation of the macrocycle is stabilized by N-H⋯N hydrogen bonds and a C-H⋯N inter-action. The benzoyl ring is inclined to the adjacent pyrrole ring by 11.66 (11)°, with a centroid-centroid distance of 3.7488 (13) Å. In the crystal, molecules are linked by N-H⋯O hydrogen bonds into helical chains propagating in [010] and C-H⋯O and C-H⋯π interactions are also observed.

Citing Articles

4-Meth-oxy-benzoyl-meso-octa-methyl-calix[2]pyrrolidino[2]pyrrole: an acyl chloride derivative of a partially reduced calix[4]pyrrole.

Journot G, Neier R, Stoeckli-Evans H Acta Crystallogr Sect E Struct Rep Online. 2012; 68(Pt 4):o929-30.

PMID: 22589993 PMC: 3343912. DOI: 10.1107/S1600536812008008.

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