N,N-Dimethyl-4-[(E)-2-(3,6,7-tribromo-9-butyl-9H-carbazol-2-yl)ethen-yl]aniline
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Abstract
In the title mol-ecule, C(26)H(25)Br(3)N(2), a dihedral angle of 6.15 (10)° is present between the carbazole and benzene ring systems with an E conformation about the C=C bond [1.335 (4) Å]. The butyl group is almost perpendicular to the carbazole plane [C-N-C-C torsion angle = -98.7 (3)°]. In the crystal, supra-molecular double chains along [-7,18,-16] are formed via C-H⋯Br and π-π inter-actions [centroid(carbazole five-membered ring)⋯centroid(carbazole six-membered ring) distance = 3.6333 (13) Å].
References
1.
Ramathilagam C, Venkatesan N, Rajakumar P, Umarani P, Manivannan V
. 9-p-Tolyl-9H-carbazole-3-carbonitrile. Acta Crystallogr Sect E Struct Rep Online. 2011; 67(Pt 10):o2796.
PMC: 3201498.
DOI: 10.1107/S1600536811039286.
View
2.
Lee W, Cho N, Kwon J, Ko J, Hong J
. New organic dye based on a 3,6-disubstituted carbazole donor for efficient dye-sensitized solar cells. Chem Asian J. 2011; 7(2):343-50.
DOI: 10.1002/asia.201100661.
View
3.
Ooyama Y, Nagano T, Inoue S, Imae I, Komaguchi K, Ohshita J
. Dye-sensitized solar cells based on donor-π-acceptor fluorescent dyes with a pyridine ring as an electron-withdrawing-injecting anchoring group. Chemistry. 2011; 17(52):14837-43.
DOI: 10.1002/chem.201101923.
View
4.
Thomas K, Lin J, Tao Y, Ko C
. Light-emitting carbazole derivatives: potential electroluminescent materials. J Am Chem Soc. 2001; 123(38):9404-11.
DOI: 10.1021/ja010819s.
View
5.
Pawluc P, Franczyk A, Walkowiak J, Hreczycho G, Kubicki M, Marciniec B
. (E)-9-(2-iodovinyl)-9H-carbazole: a new coupling reagent for the synthesis of π-conjugated carbazoles. Org Lett. 2011; 13(8):1976-9.
DOI: 10.1021/ol200350a.
View