Charge Photogeneration in Hybrid Solar Cells: a Comparison Between Quantum Dots and in Situ Grown CdS

We demonstrate that blend films containing poly(3-hexylthiophene-2,5-diyl) and in situ grown CdS display a greater yield of photogenerated charges than a blend containing an equivalent amount of pre-synthesised CdS quantum dots. Moreover, we show that the greater charge yield in the in situ grown films leads to an improvement in device efficiency. The present findings also appear to suggest that charge photogeneration at the CdS/polymer heterojunction is facilitated by the formation of nanoparticle networks as a result of CdS aggregation.