» Articles » PMID: 22159296

Unusual Coordination Mode of Tetradentate Schiff Base Cobalt(III) Complexes

Overview
Journal Dalton Trans
Specialty Chemistry
Date 2011 Dec 14
PMID 22159296
Citations 1
Authors
Affiliations
Soon will be listed here.
Abstract

Contrary to the stereotype, Jacobsen's catalyst, chiral (salcy)Co(III)OAc adopts an unusual binding mode. The tetradentate {ONNO} ligand does not form a square plane but wraps cobalt in a cis-β fashion while acetate is chelating.

Citing Articles

Theoretical study on preference of open polymer vs. cyclic products in CO/epoxide copolymerization with cobalt(III)-salen bifunctional catalysts.

Roznowska A, Dyduch K, Lee B, Michalak A J Mol Model. 2020; 26(6):113.

PMID: 32378131 PMC: 7203596. DOI: 10.1007/s00894-020-04364-x.