(1R,2R,3R,4S,5S)-3-Methyl-8-oxa-bicyclo-[3.2.1]oct-6-ene-2,4-diyl Diacetate
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Abstract
The mol-ecule of the title compound, C(12)H(16)O(5), has crystallographically imposed mirror symmetry with the mirror plane passing through the endocyclic O atom and the mid-point of the double bond. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds, forming chains running along the a axis.
References
1.
Tamayo J, Franco F, Lo Re D, Sanchez-Cantalejo F
. Synthesis of pentahydroxylated pyrrolizidines and indolizidines. J Org Chem. 2009; 74(15):5679-82.
DOI: 10.1021/jo900801c.
View
2.
Hoffmann H, Dunkel R, Mentzel M, Reuter H, Stark C
. The total synthesis of C-glycosides with completely resolved seven-carbon backbone polyol stereochemistry: stereochemical correlations and access to L-configured and other rare carbohydrates. Chemistry. 2002; 7(22):4771-89.
DOI: 10.1002/1521-3765(20011119)7:22<4771::aid-chem4771>3.0.co;2-j.
View
3.
Tafeenko V, Aslanov L, Proskurnina M, Sosonyuk S, Khlevin D
. 3-exo-Chloro-8-oxabicyclo-[3.2.1]oct-6-ene-2,4-diol chloro-form 0.33-solvate. Acta Crystallogr Sect E Struct Rep Online. 2011; 65(Pt 7):o1580.
PMC: 2969453.
DOI: 10.1107/S1600536809021898.
View
4.
Schwenter M, Vogel P
. From 2,2'-methylenedifuran to all stereomeric pentadecane-1,3,5,7,9,11,13,15-octols. J Org Chem. 2001; 66(23):7869-72.
DOI: 10.1021/jo010172u.
View
5.
Meilert K, Schwenter M, Shatz Y, Reddy Dubbaka S, Vogel P
. Scope and limitations of the double [4+3]-cycloadditions of 2-oxyallyl cations to 2,2'-methylenedifuran and derivatives. J Org Chem. 2003; 68(7):2964-7.
DOI: 10.1021/jo020678s.
View