Ruthenium-catalyzed Oxidation of a Carbon-carbon Triple Bond: Facile Syntheses of Alkenyl 1,2-diketones from Alkynes
Overview
Overview
Journal
Dalton Trans
Publisher
Royal Society of Chemistry
Specialty
Chemistry
Date
2011 Oct 22
PMID
22015646
Citations
1
Authors
Authors
Affiliations
Affiliations
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Abstract
A new oxidation procedure of alkynes catalyzed by Tp(PPh(3))(CH(3)CN)Ru-Cl is presented, which provides an efficient way to obtain alkenyl 1,2-diketones via ruthenium alkenyl 1,2-diketone intermediates. In contrast, the analogous reactions with Tp(PPh(3))(PhCN)Ru-Cl gave rise to the ruthenium metallacycle complexes.
Citing Articles
Buil M, Esteruelas M, Onate E, Picazo N Organometallics. 2022; 40(24):4150-4162.
PMID: 35264819 PMC: 8895684. DOI: 10.1021/acs.organomet.1c00621.