Synthesis and Optical Resolution of a Cu(I) Double-stranded Helicate with Ketimine-bridged Tris(bipyridine) Ligands

Overview

Journal Chem Commun (Camb)

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2011 Aug 6

PMID 21818481

Citations 5

Authors

Yoshio Furusho

Hidetoshi Goto

Ken Itomi

Hiroshi Katagiri

Toyoharu Miyagawa

Eiji Yashima

Affiliations

Soon will be listed here.

Abstract

A tetranuclear Cu(I) double-stranded helicate was synthesized from ketimine-bridged tris(bipyridine) ligands and Cu(I) ions, and the racemate was successfully resolved by diastereomeric salt formation using an optically pure phosphate anion followed by anion exchange with NaPF(6) without racemization.

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