Ring Strain-promoted Allylic Transposition of Cyclic Silyl Ethers

Overview

Journal Org Lett

Publisher American Chemical Society

Specialties Biochemistry
Chemistry

Date 2011 Jun 9

PMID 21648455

Citations 6

Authors

Ivan Volchkov

Sangho Park

Daesung Lee

Affiliations

Soon will be listed here.

Abstract

Relief of the ring strain of medium-sized rings promotes a regioselective allylic transposition of a C-O bond when catalyzed by rhenium oxide. Through the allylic transposition, eight-membered cyclic silyl ethers undergo ring contraction to the corresponding six-membered siloxacycles.

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