Mobilizing Cu(I) for Carbon-carbon Bond Forming Catalysis in the Presence of Thiolate. Chemical Mimicking of Metallothioneins

Overview

Journal J Am Chem Soc

Publisher American Chemical Society

Specialty Chemistry

Date 2011 Apr 1

PMID 21449537

Citations 5

Authors

Zhihui Zhang

Matthew G Lindale

Lanny S Liebeskind

Affiliations

Soon will be listed here.

Abstract

Copper(I) is rendered catalytically viable in the presence of thiolate by the design of a small molecule chemical analogue of the metallothionein system in which an N-O reactant serves the same conceptual purpose of the S-S reactant of the biological system.

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