Supramolecular Control on Chemo- and Regioselectivity Via Encapsulation of (NHC)-Au Catalyst Within a Hexameric Self-assembled Host

Overview

Journal J Am Chem Soc

Publisher American Chemical Society

Specialty Chemistry

Date 2011 Feb 16

PMID 21319822

Citations 23

Authors

Alessandra Cavarzan

Alessandro Scarso

Paolo Sgarbossa

Giorgio Strukul

Joost N H Reek

Affiliations

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Abstract

The encapsulation of a Au(I) catalyst within a self-assembled, hydrogen bonded, hexameric capsule dramatically changes its catalytic activity, leading to unusual products due to the steric requirements of the host's cavity.

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