Face-directed Self-assembly of an Electronically Active Archimedean Polyoxometalate Architecture

Overview

Journal Nat Chem

Specialty Chemistry

Date 2010 Dec 3

PMID 21124513

Citations 20

Authors

Scott G Mitchell

Carsten Streb

Haralampos N Miras

Thomas Boyd

De-Liang Long

Leroy Cronin

Affiliations

Soon will be listed here.

Abstract

The convergent assembly of metal-organic frameworks has enabled the design of porous materials using a structural building unit approach, but functional systems incorporating pre-assembled structural building unit 'pore' openings are rare. Here, we show that the face-directed assembly of a ring-shaped macrocyclic polyoxometalate structural building unit, {P(8)W(48)O(184)}(40-) with an integrated 1-nm pore as an 'aperture synthon', with manganese linkers yields a vast three-dimensional extended framework architecture based on a truncated cuboctahedron. The 1-nm-diameter entrance pores of the {P(8)W(48)O(184)}(40-) structural building unit lead to approximately spherical 7.24-nm(3) cavities containing exchangeable alkali-metal cations that can be replaced by transition-metal ions through a cation exchange process. Control over this process can be exerted by either electrochemically switching the overall framework charge by manipulating the oxidation state of the manganese linker ions, or by physically gating the pores with large organic cations, thus demonstrating how metal-organic framework-like structures with integrated pores and new physical properties can be assembled.

Citing Articles

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