Ordered Mesoporous Materials As Solid Supports for Rhodium-diphosphine Catalysts with Remarkable Hydroformylation Activity

Overview

Journal Chem Commun (Camb)

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2010 Aug 11

PMID 20697633

Citations 1

Authors

Fabrizio Marras

Jia Wang

Marc-Olivier Coppens

Joost N H Reek

Affiliations

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Abstract

A rhodium-diphosphine complex based on Xantphos-type ligands was anchored on mesoporous silica SBA-15, and the material showed remarkably high catalytic activity in the hydroformylation of 1-octene, even exceeding its homogeneous analogue under certain conditions.

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PMID: 34672398 PMC: 9299010. DOI: 10.1002/chem.202103099.