Electrochemical Sensing Systems for Arsenate Estimation by Oxidation of L-cysteine

In this study, rapid electrochemical sensing systems for detection of arsenate by oxidation of L-cysteine are proposed. Three different sensing systems comprising of screen-printed electrode and standard electrodes were used for this study. The detector element i.e. L-cysteine was immobilized on the working electrodes of the transducers by in-situ polymerization of acylamide. The electrocatalytic oxidation of L-cysteine was performed by cyclic voltammentry and amperometry. All the systems presented linear response range up to 30 microgL(-1) of arsenic. The sensors were able to estimate arsenic below 10 microgL(-1) with a detection limit of 1.2-4.6 microgL(-1).