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Molecular Rearrangements in the Construction of Complex Molecules

Overview
Journal Tetrahedron
Specialty Chemistry
Date 2010 Jul 20
PMID 20640042
Citations 18
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Abstract

A personal account is given of the development in my laboratory of designed molecular rearrangements and their application in target-directed synthesis.

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References
1.
Baran P, Hafensteiner B, Ambhaikar N, Guerrero C, Gallagher J . Enantioselective total synthesis of avrainvillamide and the stephacidins. J Am Chem Soc. 2006; 128(26):8678-93. DOI: 10.1021/ja061660s. View

2.
Breslow R, Baldwin S, Flechtner T, Kalicky P, Liu S, Washburn W . Remote oxidation of steroids by photolysis of attached benzophenone groups. J Am Chem Soc. 1973; 95(10):3251-62. DOI: 10.1021/ja00791a031. View

3.
Brummond K, Hong S . A formal total synthesis of (-)-FR901483, using a tandem cationic aza-Cope rearrangement/Mannich cyclization approach. J Org Chem. 2005; 70(3):907-16. DOI: 10.1021/jo0483567. View

4.
Watson M, Overman L, Bergman R . Kinetic and computational analysis of the palladium(II)-catalyzed asymmetric allylic trichloroacetimidate rearrangement: development of a model for enantioselectivity. J Am Chem Soc. 2007; 129(16):5031-44. DOI: 10.1021/ja0676962. View

5.
Armstrong A, Bhonoah Y, Shanahan S . Aza-Prins-pinacol approach to 7-azabicyclo[2.2.1]heptanes: syntheses of (+/-)-epibatidine and (+/-)-epiboxidine. J Org Chem. 2007; 72(21):8019-24. DOI: 10.1021/jo701536a. View