Chemiluminescence from Reactions with Bis-cyclometalated Iridium Complexes in Acidic Aqueous Solution

Overview

Journal Analyst

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2009 Jun 30

PMID 19562192

Citations 4

Authors

Reshmi V Kiran

Elizabeth M Zammit

Conor F Hogan

Bruce D James

Neil W Barnett

Paul S Francis

Affiliations

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Abstract

Chemical reactions between certain bis-cyclometalated iridium complexes, cerium(IV) and organic reducing agents in aqueous solution produce an emission of light which in some cases is more intense than that from analogous reactions with conventional ruthenium-based reagents, thus providing a new avenue for chemically-initiated luminescence detection.

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