Asymmetric Tandem Michael Addition-ylide Olefination Reaction for the Synthesis of Optically Active Cyclohexa-1,3-diene Derivatives

Overview

Journal Chem Commun (Camb)

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2009 May 23

PMID 19462097

Citations 7

Authors

Long-Wu Ye

Shou-Bing Wang

Qing-Gang Wang

Xiu-Li Sun

Yong Tang

Yong-Gui Zhou

Affiliations

Soon will be listed here.

Abstract

The reaction of a crotonate-derived chiral phosphonium salt with alpha,beta-unsaturated carbonyl compounds in the presence of Cs(2)CO(3) affords optically active cyclohexa-1,3-diene derivatives with up to 90% ee in good yields.

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