[{(eta(5)-C(5)Me(5))(2)Sm}(4)P(8)]: a Molecular Polyphosphide of the Rare-earth Elements

Overview

Journal J Am Chem Soc

Publisher American Chemical Society

Specialty Chemistry

Date 2009 Apr 8

PMID 19348485

Citations 12

Authors

Sergey N Konchenko

Nikolay A Pushkarevsky

Michael T Gamer

Ralf Koppe

Hansgeorg Schnockel

Peter W Roesky

Affiliations

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Abstract

[{(eta(5)-C(5)Me(5))(2)Sm}(4)P(8)], a molecular polyphosphide of the rare-earth elements having a realgar core structure, was synthesized by a one-electron redox reaction of divalent samarocen and white phosphorus.

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