Alpha 2.0
Login Register
» Articles » PMID: 17406692

Bis(permethylpentalene)cerium--another Ambiguity in Lanthanide Oxidation State

Overview
Journal Chem Commun (Camb)
Publisher Royal Society of Chemistry
Specialty Chemistry
Date 2007 Apr 5
PMID 17406692
Citations 6
Authors
Andrew Ashley
Gabor Balazs
Andrew Cowley
Jennifer Green
Corwin H Booth
Dermot OHare
Affiliations
Soon will be listed here.
Abstract

Ce(eta(8)-C(8)Me(6))(2) exists in a valency close to Ce(iii) with some Ce(iv) and provides an example of the Kondo effect in a discrete molecule.

Citing Articles

The Counterintuitive Relationship between Orbital Energy, Orbital Overlap, and Bond Covalency in CeF and CeCl.

Branson J, Smith P, Sergentu D, Russo D, Gupta H, Booth C J Am Chem Soc. 2024; 146(37):25640-25655.

PMID: 39241121 PMC: 11421006. DOI: 10.1021/jacs.4c07459.

Tetraphenylpentalenide organolanthanide complexes.

Katzer N, Kaur M, Sen A, Nimaiyar R, Autschbach J, Arnold P Chem Commun (Camb). 2024; 60(72):9749-9752.

PMID: 39171542 PMC: 11513172. DOI: 10.1039/d4cc02570a.

Back to the future of organolanthanide chemistry.

Mahieu N, Piatkowski J, Simler T, Nocton G Chem Sci. 2023; 14(3):443-457.

PMID: 36741512 PMC: 9848160. DOI: 10.1039/d2sc05976b.

Electronic structure studies reveal 4f/5d mixing and its effect on bonding characteristics in Ce-imido and -oxo complexes.

Moreau L, Lapsheva E, Amaro-Estrada J, Gau M, Carroll P, Manor B Chem Sci. 2022; 13(6):1759-1773.

PMID: 35282640 PMC: 8827158. DOI: 10.1039/d1sc06623d.

The duality of electron localization and covalency in lanthanide and actinide metallocenes.

Smiles D, Batista E, Booth C, Clark D, Keith J, Kozimor S Chem Sci. 2021; 11(10):2796-2809.

PMID: 34084340 PMC: 8157540. DOI: 10.1039/c9sc06114b.