Iridium-catalyzed Conversion of Alcohols into Amides Via Oximes

Overview

Journal Org Lett

Publisher American Chemical Society

Specialties Biochemistry
Chemistry

Date 2006 Dec 29

PMID 17192088

Citations 9

Authors

Nathan A Owston

Alexandra J Parker

Jonathan M J Williams

Affiliations

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Abstract

[reaction: see text] The iridium catalyst [Ir(Cp*)Cl2]2 is effective for the rearrangement of oximes to furnish amides. The reaction has been combined with catalytic transfer hydrogenation between an alcohol and alkene to allow the conversion of alcohols into amides in a one-pot process.

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