A Key Step in the Formation of Acrylic Acid from CO2 and Ethylene: the Transformation of a Nickelalactone into a Nickel-acrylate Complex

Overview

Journal Chem Commun (Camb)

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2006 Jun 8

PMID 16758032

Citations 3

Authors

Reinald Fischer

Jens Langer

Astrid Malassa

Dirk Walther

Helmar Gorls

Gavin Vaughan

Affiliations

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Abstract

The reaction of a nickelalactone with dppm, resulting in the formation of a stable binuclear Ni(I) complex with an acrylate, a Ph2P- and a dppm bridge, models a key step in the formation of acrylic acid from CO2 and ethylene.

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