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Ring-current Models from the Differential Biot-Savart Law

Overview
Journal Org Lett
Specialties Biochemistry
Chemistry
Date 2004 Nov 19
PMID 15548048
Citations 4
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Abstract

The differential Biot-Savart law provides simple models for the pi ring currents induced in diatropic and paratropic planar conjugated molecules by a perpendicular magnetic field. The model predictions are confirmed by ab initio maps of nuclear magnetic shielding density. The effects on the protons and on the ring carbon atoms from the closest and furthest segments of the current loop are easily interpreted. [structure: see text]

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