On Early Events in the Pauson-Khand Reaction

Overview

Journal Org Lett

Publisher American Chemical Society

Specialties Biochemistry
Chemistry

Date 2003 Oct 24

PMID 14572252

Citations 6

Authors

Yves Gimbert

Denis Lesage

Anne Milet

Francoise Fournier

Andrew E Greene

Jean-Claude Tabet

Affiliations

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Abstract

[reaction: see text]. The Magnus Pauson-Khand (PK) mechanism has been studied for the first time by electrospray ionization coupled to tandem mass spectrometry. It has been found that loss of CO from the PK complex precedes olefin coordination and insertion.

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