» Articles » PMID: 12689139

Critique of Q-entropy for Thermal Statistics

Overview
Date 2003 Apr 12
PMID 12689139
Citations 7
Authors
Affiliations
Soon will be listed here.
Abstract

During the past 12 years there have been numerous papers on a relation between entropy and probability which is nonadditive and has a parameter q that depends on the nature of the thermodynamic system under consideration. For q=1 this relation corresponds to the Boltzmann-Gibbs entropy, but for other values of q it is claimed that it leads to a formalism that is consistent with the laws of thermodynamics. However, it is shown here that the joint entropy for systems having different values of q is not defined in this formalism, and consequently fundamental thermodynamic concepts such as temperature and heat exchange cannot be considered for such systems. Moreover, for q not equal 1 the probability distribution for weakly interacting systems does not factor into the product of the probability distribution for the separate systems, leading to spurious correlations and other unphysical consequences, e.g., nonextensive energy, that have been ignored in various applications given in the literature.

Citing Articles

Look Beyond Additivity and Extensivity of Entropy for Black Hole and Cosmological Horizons.

Da Browski M Entropy (Basel). 2024; 26(10).

PMID: 39451892 PMC: 11507278. DOI: 10.3390/e26100814.


Open Problems within Nonextensive Statistical Mechanics.

Nelson K Entropy (Basel). 2024; 26(2).

PMID: 38392372 PMC: 10888069. DOI: 10.3390/e26020118.


Observations of the Outer Heliosphere, Heliosheath, and Interstellar Medium.

Richardson J, Burlaga L, Elliott H, Kurth W, Liu Y, von Steiger R Space Sci Rev. 2022; 218(4):35.

PMID: 35664862 PMC: 9156517. DOI: 10.1007/s11214-022-00899-y.


Entropy, Information, and the Updating of Probabilities.

Caticha A Entropy (Basel). 2021; 23(7).

PMID: 34356436 PMC: 8307993. DOI: 10.3390/e23070895.


Superstatistical model of bacterial DNA architecture.

Bogachev M, Markelov O, Kayumov A, Bunde A Sci Rep. 2017; 7:43034.

PMID: 28225058 PMC: 5320525. DOI: 10.1038/srep43034.