Fate of Resin Acids in Pulp Mill Secondary Treatment Systems

Profiles of resin and fatty acids (RFAs), COD, and aquatic toxicity were measured across the secondary treatment systems of three pulp mills. The RFAs sorb to suspended solids, principally fiber, and are partially removed through settling. An activated sludge system is more efficient in removing RFAs than an aerated stabilization basin (ASB) because of its higher solids level. Dehydroabietic acid accounts for a significant fraction of the effluent toxicity in the two ASBs studied. The microorganisms in an ASB are unable to respond rapidly to an RFA spill, and effluent toxicity can be elevated for a prolonged period because of hydraulic backmix. The applicability of several laboratory studies to field situations is assessed.