Microwave-accelerated Ruthenium-catalyzed Olefin Metathesis

Overview

Journal Org Lett

Publisher American Chemical Society

Specialties Biochemistry
Chemistry

Date 2002 Apr 27

PMID 11975630

Citations 9

Authors

Kelly G Mayo

Eliza H Nearhoof

James J Kiddle

Affiliations

Soon will be listed here.

Abstract

[reaction: see text]. Microwave heating is an efficient method for the acceleration of ring-closing metathesis reactions using ruthenium-based catalysts. The reaction can be rapidly conducted in either ionic liquids, such as 1-butyl-3-methylimidazolium tetrafluoroborate (bmim), or in a microwave transparent solvent (MTS) such as dichloromethane.

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Ammonium-tagged ruthenium-based catalysts for olefin metathesis in aqueous media under ultrasound and microwave irradiation.

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Metathesis of fatty acid ester derivatives in 1,1-dialkyl and 1,2,3-trialkyl imidazolium type ionic liquids.

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